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Stefan Bernhard - Department of Chemistry

Stefan Bernhard

Professor, Department of Chemistry

Stefan Bernhard is interested in interconverting radiative and electrochemical energy through the use of transition metal complexes.

Expertise

Topics:  Energy, Organic Light Emitting Devices, Luminescent Materials, Solar Fuels, Organic Photovoltaics, Circular Polarized Luminescence

Industries: Research, Education/Learning, Chemicals

Stefan Bernhard started his chemistry career as a laboratory technician with Chocolat Tobler, which was followed by a degree in chemical engineering from the Ingenieurschule Burgdorf. Further endeavors were rewarded with a diploma and a Ph.D. in chemistry. These studies were complemented by a laser spectroscopy project at Los Angeles National Laboratory and time in the Abruña Group at Cornell University focused on electrochemistry. His first faculty appointment at Princeton University explored luminescent metal complexes for optoelectronic and solar conversion applications. In 2014, he was promoted to the rank of Professor at Carnegie Mellon University where he founded the Bernhard Research Group. The Bernhard Group's research includes luminescent materials, solar fuels, organic photovoltaics, organic light emitting devices, and circular polarized luminescence.

The Bernhard lab is interested in interconverting radiative and electrochemical energy through the use of transition metal complexes with electronically tunable architectures. That is, they study both the absorption of light to generate electrochemical potential (organic photovoltaics and artificial photosynthesis) as well as the emanation of light using electrical current (organic light emitting devices). The Bernhard lab is also deeply involved in the exploration of chiral luminophores (and chiral ensembles) that emit circularly polarized light. Their work in this area has produced cutting-edge tools for both the characterization and prediction of polarized luminescence. In each of the above areas, it is our aspiration to precisely understand and administer the interactions that control ensemble properties by establishing clear structure-activity relationships.

Media Experience

Designer catalyst with enzyme-like cavity splits water almost as fast as plants  — Chemistry World
‘It is very hard to oxidise water,’ explains Stefan Bernhard, a renewable energy chemist at Carnegie Mellon University, US. ‘The process requires the transfer of four electrons and so needs a lot of electrochemical or photochemical energy. One of the particularly tricky aspects is ensuring that the catalyst isn’t just “burnt up” by these demanding conditions.’

Bernhard Designs Materials for Energy, Electronics of the Future  — Carnegie Mellon University Mellon College of Science
Stefan Bernhard, Scott Institute Energy fellow and Carnegie Mellon University chemistry professor, conducts research on converting sunlight into fuel, which has been the driving force of his work since his undergraduate career.

Education

Ph.D., Chemistry, Université de Fribourg, Switzerland
Diploma, Chemical Engineering, School of Engineering, Burgdorf, Switzerland
Diploma, Chemistry, University of Fribourg, Switzerland

Accomplishments

Graduate Mentoring Award (2006 Princeton University)

National Science Foundation CAREER Award (2005)

Dreyfus New Faculty Award (2002)

Links

Articles

Synthesis and Structure of an Ion-Exchanged SrTiO3 Photocatalyst with Improved Reactivity for Hydrogen Evolution —  Advanced Materials Interfaces

Photogeneration of Hydrogen from Glycerol and Other Oxygenates Using Molecular Photocatalysts and In Situ Produced Nanoparticulate Cocatalysts —  ACS Sustainable Chemistry & Engineering

Identifying limitations in screening high-throughput photocatalytic bimetallic nanoparticles with machine-learned hydrogen adsorptions —  Applied Catalysis B: Environmental

Reinterpreting the Fate of Iridium(III) Photocatalysts─Screening a Combinatorial Library to Explore Light-Driven Side-Reactions —  Journal of the American Chemical Society

Ligand Enhanced Activity of In Situ Formed Nanoparticles for Photocatalytic Hydrogen Evolution —  ChemCatChem

Photos